A joint project of the Graduate School, Peabody College, and the Jean & Alexander Heard Library

Title page for ETD etd-11142019-195144

Type of Document Dissertation
Author Wang, Li
Author's Email Address li.wang.1@vanderbilt.edu
URN etd-11142019-195144
Title Energy Efficiency, Performance Analysis and Multiscale Modelling of Capacitive Deionization
Degree PhD
Department Environmental Engineering
Advisory Committee
Advisor Name Title
Shihong Lin Committee Chair
Alan Bowers Committee Member
George Hornberger Committee Member
Kelsey Hatzell Committee Member
Peter Pintauro Committee Member
  • modelling
  • performance improvement
  • energy efficiency
  • Capacitive deionization
Date of Defense 2019-11-05
Availability restrictsix
Capacitive deionization (CDI) is an emerging technology that utilizes the electrical field between two electrodes to remove the ions from the salty waters. The ions are stored in the electrical double layers (EDLs) forming at the interface between the electrode matrix and the aqueous solution. Until now, numerous effort has been devoted to studying the ion transport mechanisms and to fabricating high-performance electrodes. Yet, there lacks a fair evaluation framework and systematic understanding of the dependences among the operational variables. In this dissertation, we start with the thermodynamically reversible cycle to show the ideal operation of CDI, followed by comparing it with the CDI operation in reality to reveal that the energy efficiency of CDI is relatively low. We move on to understanding the energy losses during the charging and discharge steps of CDI. The quantification of the energetic-kinetic tradeoff for CDI demonstrates that the energetic efficiency cannot be divorced from the kinetic efficiency. We then employ the tradeoff curve to evaluate the two commonly used charging method, i.e. constant voltage and constant current, of CDI, and found out that which is better depends on the separation scenarios. In order to reduce the energy consumption, we decrease the impedance of electrode macropores by filling with conductive polyelectrolytes, with which the energy consumption saves up to half of that in membrane CDI. In the last chapter, we model the continuous operation of flow electrode CDI (FCDI) with an equivalent model that considering the flow electrodes as film electrodes rotating around the electrode chamber. The model successfully capture the phenomelogical characteristics of FCDI including effluent concentration, current density and cell voltages. In summary, this dissertation introduces the framework for CDI performance evaluation, and demonstrates the effective direction to improve the performance.
  Filename       Size       Approximate Download Time (Hours:Minutes:Seconds) 
 28.8 Modem   56K Modem   ISDN (64 Kb)   ISDN (128 Kb)   Higher-speed Access 
[campus] Dissertation_Wang_Li.pdf 5.10 Mb 00:23:36 00:12:08 00:10:37 00:05:18 00:00:27
[campus] indicates that a file or directory is accessible from the campus network only.

Browse All Available ETDs by ( Author | Department )

If you have more questions or technical problems, please Contact LITS.