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Title page for ETD etd-03312010-132550


Type of Document Dissertation
Author Gosnell, Jonathan David
Author's Email Address jonathan.d.gosnell@vanderbilt.edu
URN etd-03312010-132550
Title A Phosphor-based Light-emitting Diode Using White-light Cadmium Selenide Nanocrystals
Degree PhD
Department Interdisciplinary Materials Science
Advisory Committee
Advisor Name Title
Sharon Weiss Committee Chair
Daniel Fleetwood Committee Member
Leonard Feldman Committee Member
Richard Haglund Committee Member
Sandra Rosenthal Committee Member
Keywords
  • quantum dot
  • LED
  • CdSe
  • phosphor
  • solid state lighting
  • optics
  • thin film
  • nanoscience
Date of Defense 2010-03-25
Availability unrestricted
Abstract
White light-emitting diodes (LEDs) have attracted great interest recently due to their capability for higher efficiency and longer lifetimes compared to other current lighting technologies. In pursuit of a white LED that has improved characteristics over commercial white LEDs, the focus of this dissertation is on the optical properties of white-light emitting cadmium selenide (CdSe) nanocrystals. Phosphor-based LEDs typically require an encapsulant to protect the phosphor from heating and photo-oxidation, as well as to inhibit particle aggregation. In this dissertation, a number of encapsulant materials were tested to determine which material would mix well with the nanocrystals in solution before deposition, cure properly as a film, and maintain the optical properties of the CdSe nanocrystals. A biphenylperfluorocylcobutyl (BP-PFCB) polymer performed the best of the encapsulants tested, with over twice the emission intensity of the next best encapsulant as well as a much higher percentage of UV excitation light absorbed at a certain thickness. In addition, several methods to improve the device efficiency of these LEDs were investigated, including experimentally optimizing the LED excitation wavelength, film thickness, and nanocrystal concentration in the film. The optimum device parameters were found to be a 365 nm or 385 nm LED exciting a film of 60-140 μm in thickness with a nanocrystal weight concentration in BP-PFCB of 10%, resulting in a luminous efficacy of 1 lm/W, CIE coordinates of (0.35, 0.37), and a color rendering index (CRI) of 86. Furthermore, while scattering from micron-sized phosphors used in LEDs can cause significant losses, the scattering cross section for ultrasmall CdSe nanocrystals was found to be five orders of magnitude lower than the absorption cross section, thus scattering from nanocrystals can be neglected. Finally, a more accurate approach to determining the nanocrystal concentration of a solution and extinction coefficient was investigated. These results represent the initial steps towards building an ultrasmall CdSe nanocrystal-based, photoluminescent LED, and with further improvements could result in higher quality lighting products.
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